Gisela M.A. Richter's Archaic Attic gravestones PDF

By Gisela M.A. Richter

In Attica, round 580 BC, a sequence of tall gravestones starts off, crowned through the determine of a sphinx, on a easily adorned capital. After the mid-century the capital is elaborated as palmettes with spirals, yet quickly thereafter the stele sort is simplified, with a palmette purely. the kind disppears within the early fifth cent. BC. such a lot figures are male and there's tough age differentiation via sort: younger as athlete, mature as warrior, previous as guy with puppy. within the final part the oblong bases for the stelai will be embellished in reduction on 3 aspects.

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Brown Copyright ¶ 2002 John Wiley & Sons, Inc. 1677, 1689 The present treatment of post-1978 literature is divided according to the nature of the heterocyclic substrate (monocyclic, bicyclic, tricyclic, or spiro); each of these broad categories is then subdivided alphabetically, with reduced substrates included with their aromatic counterparts. Cyclic anhydrides, cyclic imides, lactones, and the like are classified as the appropriate heterocyclic derivatives. 5. 1. PYRAZINES FROM OTHER HETEROMONOCYCLIC SYSTEMS (H 53) Such syntheses can occur by ring expansion, ring contraction, rearrangement, ring fission (with or without subsequent elaboration), fragmentation with subsequent elaboration, or combination with a second synthon followed by other reactions.

J. Brown Copyright ¶ 2002 John Wiley & Sons, Inc. 1677, 1689 The present treatment of post-1978 literature is divided according to the nature of the heterocyclic substrate (monocyclic, bicyclic, tricyclic, or spiro); each of these broad categories is then subdivided alphabetically, with reduced substrates included with their aromatic counterparts. Cyclic anhydrides, cyclic imides, lactones, and the like are classified as the appropriate heterocyclic derivatives. 5. 1. PYRAZINES FROM OTHER HETEROMONOCYCLIC SYSTEMS (H 53) Such syntheses can occur by ring expansion, ring contraction, rearrangement, ring fission (with or without subsequent elaboration), fragmentation with subsequent elaboration, or combination with a second synthon followed by other reactions.

97, cf. 1307, cf. 753, 754 H2C H2 C NH2 NH2 (168) HO , [O] OCMe PhN CBui (169) N Me N Bui (170) Ethylenediamine and phenyl-or thien-2-ylglyoxal gave the respective unisolated dihydropyrazines (172, R ϭ Ph or thien-2-yl). C synthon. In every case only one product was isolated, usually that arising from condensation of the free amino group with the ketonic carbonyl and the amidic amino group with the aldehydic carbonyl. 1502 NC N C CPh NC N C CSiPri3 (177) NCC NH2 NC N CF3 NH2 NC N C6H5Me-p (178) NC N C6H4(CH2Br)-p NC N C6H4(CH2Br)-p (180) NCC (179) 26 Primary Syntheses from Aliphatic or Carbocyclic Systhons Ethylenediamine and p, pЈ-dimethoxybenzil gave 2,3-bis(p-methoxyphenyl)-5,6dihydropyrazine (181) (EtOH, 20° : reflux, 30 min: 88%)1065, cf.

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Archaic Attic gravestones by Gisela M.A. Richter


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